NMR Spectroscopy: New Methods and Applications

✍ Scribed by George C. Levy (Eds.)

• Publisher: American Chemical Society
• Year: 1982
• Tongue: English
• Leaves: 382
• Series: ACS Symposium Series 191
• Category: Library

✦ Synopsis

Content: Ultra high-field NMR / Felix W. Wehrli --
NMR spectroscopy at 600 MHz / A.A. Bothner-By and J. Dadok --
The information content of two-dimensional Fourier spectroscopy / R.R. Ernst --
Quadrupolar metallic nuclei : ²³Na NMR studies of cation binding by natural and synthetic ionophores / Pierre Laszlo --
Deuterium NMR spectroscopy / Ian C.P. Smith and Henry H. Mantsch --
NMR of ¹³C enriched amino acids and peptides / Robert E. London --
The study of the metabolism of 13C labeled substrates by ¹³C NMR spectroscopy of intact cells, tissues, and organs / N.A. Matwiyoff, R.E. London, and J.Y. Hutson --
Chemical bond labeling and double cross-polarization NMR / Jacob Schaefer, E.O. Stejskal, and R.A. McKay --
NMR spectroscopy at high pressure / Jiri Jonas --
¹³C cross-polarization magic-angle spinning NMR study : amines adsorbed on [gamma]-alumina utilizing a unique spinner design / William H. Dawson, Steve W. Kaiser, Ruth R. Inners, F. David Doty, and Paul D. Ellis --
Solid state NMR of linear and cyclic peptides / L.M. Gierasch, M.H. Frey, J.G. Hexem, and S.J. Opella --
³¹P NMR studies of DNA conformation and dynamics / Jack S. Cohen and Chi-Wan Chen --
Multiple field natural abundance ¹³C NMR studies of DNA dynamics / Peter R. Hilliard, Randolph L. Rill, George C. Levy, and Linda F. Levy --
Photochemically induced dynamic nuclear polarization (Photo-CIDNP) of biological molecules using continuous wave and time-resolved methods / P.J. Hore and R. Kaptein --
¹³C NMR characterization of solid fossil fuels using cross-polarization and magic-angle spinning / Gary E. Maciel and Mark J. Sullivan --
Solid state ¹³C NMR studies of polyester thermoplastic elastomers / Lynn W. Jelinski, Joseph J. Dumais, F.C. Schilling, and F.A. Bovey.

✦ Table of Contents

Title Page
......Page 1
Half Title Page
......Page 3
Copyright
......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 Introduction......Page 8
LITERATURE CITED......Page 12
2 Ultra High-Field NMR......Page 13
Magnet Technology......Page 15
Instrumental Requirements at Very High Field......Page 20
Typical Applications......Page 25
LITERATURE CITED......Page 35
3 NMR Spectroscopy at 600 MHz......Page 36
Literature Cited......Page 49
4 The Information Content of Two-Dimensional Fourier Spectroscopy......Page 51
LITERATURE CITED......Page 64
5 Quadrupolar Metallic Nuclei 23Na NMR Studies of Cation Binding by Natural and Synthetic Ionophores......Page 66
Theoretical Background: Dual Relaxation of a Spin 3/2 Particle......Page 67
Experimental Procedure and Data Analysis......Page 69
Application to Structure Reactivity Correlations......Page 73
Site Binding or Atmospheric Condensation Polyelectrolytes......Page 74
Results for Ionophore Antibiotics......Page 79
Cation-Binding Muscular Proteins......Page 82
Structures Maintained by Na+- Binding: The 5+-GMP Supramolecular Assembly......Page 88
23Na NMR Whole Tissue......Page 91
LITERATURE CITED......Page 93
Magnetic Properties of Deuterium......Page 99
High Resolution Deuterium NMR......Page 102
Deuterium Nuclear Relaxation......Page 108
Wide-line Deuterium NMR......Page 111
References......Page 118
Spectral Characteristics of 13C Enriched Amino Acids......Page 120
Conformational Interpretation of Scalar Carbon-Carbon Coupling Constants.......Page 128
Relaxation Behavior of 13C Enriched Amino Acids.......Page 139
Biological Studies with Istopically Labeled Amino Acids and Peptides......Page 149
Future Developments......Page 151
LITERATURE CITED.......Page 152
8 The Study of the Metabolism of 13C Labeled Substrates by 13C NMR Spectroscopy of Intact Cells, Tissues, and Organs......Page 157
Methodology......Page 160
Applications......Page 171
Prospects for Future Developments......Page 182
Literature Cited......Page 183
9 Chemical Bond Labeling and Double Cross-Polarization NMR......Page 187
NMR Apparatus......Page 188
Specific Double Labels: Soybean Organ Cultures......Page 190
Non-Specific Double Labels: Protein Turnover in Soybean Leaves......Page 195
Conclusions and Projections......Page 197
Literature Cited......Page 198
Multinuclear High Resolution FT NMR at High Pressure......Page 199
Relaxation and Transport Behavior of Compressed Supercritical Water......Page 207
Dynamic Structure of Disordered Materials......Page 209
Literature Cited......Page 217
11 13C Cross-Polarization Magic-Angle Spinning NMR Study Amines Adsorbed on γ-Alumina Utilizing a Unique Spinner Design......Page 218
Experimental......Page 219
The 13C NMR of Amines on γ-Alumina......Page 223
Conclusions and Prospects for the Future Research......Page 227
LITERATURE CITED......Page 228
12 Solid State NMR of Linear and Cyclic Peptides......Page 231
Conformational Analysis of Isotropic Chemical Shifts......Page 232
Dynamical Analysis of Lineshapes......Page 237
Conformational Analysis of 14N-13C Dipolar Couplings......Page 239
Literature Cited......Page 244
13 31P NMR Studies of DNA Conformation and Dynamics......Page 246
Allernating B-DNA......Page 247
Dynamics
......Page 257
Telestability......Page 260
Acknowledgement......Page 262
Literature Cited......Page 263
14 Multiple Field Natural Abundance 13C NMR Studies of DNA Dynamics......Page 265
Literature Cited......Page 278
15 Photochemically Induced Dynamic Nuclear Polarization (Photo-CIDNP) of Biological Molecules Using Continuous Wave and Time-Resolved Methods......Page 280
The Radical Pair Mechanism of CIDNP......Page 281
Cyclic Reactions and Cancellation......Page 285
Photo CIDNP of Biological Molecules......Page 298
Time Resolved Photo-CIDNP......Page 307
Literature cited......Page 312
16 13C NMR Characterization of Solid Fossil Fuels Using Cross-Polarization and Magic-Angle Spinning......Page 314
Coals......Page 318
Oil Shales......Page 322
Structural Resolution......Page 331
Summary and Conclusions......Page 335
References and Footnotes......Page 337
Solid State 13C NMR Studies of Polyester Thermoplastic Elastomers......Page 339
Experimental Section......Page 340
Results — Mobile Domains......Page 342
Results — Rigid Domains......Page 347
Discussion......Page 351
Literature Cited......Page 353
A......Page 355
B
......Page 356
C
......Page 357
D
......Page 362
F
......Page 365
G
......Page 366
H
......Page 367
I
......Page 368
L
......Page 369
M
......Page 370
N
......Page 372
P
......Page 373
R
......Page 376
S
......Page 377
T
......Page 380
V
......Page 381
Z
......Page 382