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NMR Relaxation of the methyl protons in the presence of chemical exchange

โœ Scribed by D. Pumpernik; A. Azman

Publisher
Elsevier Science
Year
1977
Weight
270 KB
Volume
11
Category
Article
ISSN
0378-4487

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โœฆ Synopsis

The calculation of longitudinal nuclear magnetic relaxation for an internally rotating methyl group attached to a symmetric top molecule has been extended taking into account the chemical exchange between two kinds of'sites in the solution. The deviations from a simple exponantial decay depends strongly on the anisotropy of reorientations at two sites and the exchange rate,

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