Proton Zcoman-and dipolar spin-lattice rekxation times and second moments have been measured in polycrystallinc SiH4 at 24 %IHz, between 90 and 3 K. Down to 25 K the classical model for molecular motion appibs; below 25 EC, quantum effects have to be taken into account.
Proton NMR solid echoes in the presence of reorientational motion
β Scribed by M. Mortimer; G. Oates; T.B. Smith
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 425 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The effect of reorientational mobon on the amplwde of the proton NMR sobd echo response loll-g a resonanl
P,(90Β°)-T-Px(900)
pulse sequence for polycrystallme be-e 1.2,3.4-d, has beeen measured as a function of temperature The results are compared wth those of a theoretical model of Isolated &polar-coupled paus of spin-f nuclei
π SIMILAR VOLUMES
The effects of nonzero radio-frequency pulse widths on the echo signals in solids with molecular motions have been investigated. It has been shown that in the slow-motion region a time position and an amplitude of the echo signal depend not only on the width of the pulse, but also on the shape of po