The effects of non-equilibrium solvation dynamics on zero-barrier photoisomerization reactions are studied theoretically. A theory based on general considerations is presented. A two-state model for the time dependence of the sink function is introduced and solved analytically for the survival proba
✦ LIBER ✦
NMR-relaxation and solvation dynamics in macromolecular solutions
✍ Scribed by Hans Sillescu; Reinhard Brüssau
- Book ID
- 103010929
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 248 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The spin-I&ice r&x&on time, T,, of deuterium is found to be eonsidewbly shortened in so!utians of pol~vinylpyrr~~idone in dcuterated solvents. An interpretation is given in terms of a simple two slate
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