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NMR isotope shift as a probe of conformation in carbocations. Determination of conformation in a cyclopentyl cation

✍ Scribed by Forsyth, David A.; Botkin, James H.


Book ID
126125818
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
302 KB
Volume
106
Category
Article
ISSN
0002-7863

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Proton lanthanide-induced shifts (LIS) were measured for Yb(fod),-dibucaine complexes in CDCl, solution. The data were used in conjunction with empirical energy calculations to determine the preferred conformations of dibucaine. The energy calculations and the LIS analysis were in agreement in showi