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NMR isotope shifts as a probe of a rapid nondegenerate equilibrium in 2-aryl-3-methyl-2-butyl cations

✍ Scribed by David A. Forsyth; Yi Pan

Book ID: 104233278
Publisher: Elsevier Science
Year: 1985
Tongue: French
Weight: 240 KB
Volume: 26
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80836-4

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✦ Synopsis

Equilibrium NMR isotope shifts can be detected for nondegenerate equilibria by comparison with intrinsic shifts in static model compounds. Such equilibrium shifts are smaller than in similar nondegenerate equilibria.

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