Abstract~Fhe thermal mobility of two paraffin waxes and lwo monoglyceridc esters, used m rigid and in impact modified PVC formulations as lubricants, has been studied by means of broad line NMR. A very useful method, based on the measurement of {he pcak-lo-pcak amplitude ol ll~c narrow line componen
NMR investigation of the solubility of some lubricants in rigid and in impact modified PVC
โ Scribed by I. Jakubowicz; S.E. Svanson
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 414 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0014-3057
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โฆ Synopsis
The solubility behaviour of two paraffin-waxes and two monoglyceride-esters normally used as lubricants in PVC-formulations have been studied with wide-line NMR for rigid and for impact modified PVC. It has been shown that the investigated lubricants have limited solubility in PVC. In the impact modified product, the monoglyceride-esters are partly dissolved in the elastomer phase and partly in the PVC-phase. The paraffin-waxes have limited solubility in the elastomer and in the PVC-phases, and a considerable amount forms a separate phase.
๐ SIMILAR VOLUMES
In the two-phase system of PVC-EVA, some co-stabilizers used in connection with metallaurates show a considerable solubility in the elastomer. It is shown that these products can be removed from the soft phase by extraction with petroleum-ether for samples in powdered form. After extraction, the deg