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NMR Experiments on Ketals. XIV Conformation of 1,3-Thioxane and 1,3-Dithiane. Equilibrium of 4,6-Dimethyl-1,3-Thioxane

✍ Scribed by J. Gelan; M. Anteunis


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
364 KB
Volume
77
Category
Article
ISSN
0037-9646

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Crystal and molecular structure of diast
✍ MichaΕ‚ W. Wieczorek; Grzegorz D. Bujacz; WiesΕ‚aw R. Majzner; Piotr P. Graczyk; M πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 262 KB πŸ‘ 2 views

The crystal and molecular structures of a pair of diastereomeric 2-diphenylthiophosphinoylcis-(4,6-dimethyl)-1,3-dithianes 2 have been determined by the X-ray method. The differences in corresponding bond distances in cis-2 and trans-2 are discussed in context of the anomeric effect operating in thi