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NMR Determination of the Structures of Peroxycobalt(III) Bleomycin and Cobalt(III) Bleomycin, Products of the Aerobic Oxidation of Cobalt(II) Bleomycin by Dioxygen

โœ Scribed by Xu, Robert X.; Nettesheim, David; Otvos, James D.; Petering, David H.


Book ID
126407994
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
991 KB
Volume
33
Category
Article
ISSN
0006-2960

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CeH510 in CH30H-HZ0 is activated towards electrophilic attack upon various alkenes by Fe(C104)'9H20, Fe(II1) bleomycin and Zn(I1) bleomycin. The results imply that direct transfer of oxygen from an Fe(V)=0 intermediate is not required in the mechanism of oxygenation by iron-containing species, and t