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Identification of the Internal Axial Ligand of HO 2 −Cobalt(III)−Bleomycin: 1 H{ 15 N} HSQC NMR Investigation of Bleomycin, Deglycobleomycin, and Their Hydroperoxide−Cobalt(III) Complexes †

✍ Scribed by Xia, Chaunwu; Försterling, F. Holger; Petering, David H.


Book ID
127220344
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
108 KB
Volume
42
Category
Article
ISSN
0006-2960

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15N, 13C and 1H NMR spectra of the 2:1 c
✍ Antonín Lyčka; Josef Jirman; Aleš Cee 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 459 KB

## Abstract The ^15^N, ^13^C and ^1^H NMR spectra of 2:1 cobalt(III) complexes of azo dyes and their ^15^N isotopomers, derived from substituted 2‐hydroxyaniline azo coupling products with acetoacetanilide, were measured. It was found that, in contrast to precursors existing fully in their hydrazon