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NMR conformational analysis of cis and trans proline isomers in the neutrophil chemoattractant, N-acetyl–proline–glycine–proline

✍ Scribed by Yi-Chien Lee; Patricia L. Jackson; Michael J. Jablonsky; Donald D. Muccio; Roswell R. Pfister; Jeffrey L. Haddox; Charnell I. Sommers; G. M. Anantharamaiah; Manjula Chaddha


Publisher
Wiley (John Wiley & Sons)
Year
2001
Tongue
English
Weight
340 KB
Volume
58
Category
Article
ISSN
0006-3525

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Thermodynamic origin of cis/trans isomer
✍ Anastasios Troganis; Ioannis P. Gerothanassis; Zafiria Athanassiou; Thomas Mavro 📂 Article 📅 2000 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 178 KB 👁 1 views

The cis/trans conformational equilibrium of the two Ac-Pro isomers of the beta-turn model dipeptide [13C]-Ac-L-Pro-D-Ala-NHMe, 98% 13C enriched at the acetyl carbonyl atom, was investigated by the use of variable temperature gradient enhanced 1H-nmr, two-dimensional (2D) 1H,1H nuclear Overhauser eff