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NMR chemical shifts of129Xe dissolved in liquid haloalkanes and their mixtures

✍ Scribed by Y. -H. Lim; A. R. Calhoun; A. D. King


Publisher
Springer Vienna
Year
1997
Tongue
English
Weight
975 KB
Volume
12
Category
Article
ISSN
0937-9347

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The adsorption isotherms and lz9Xe NMR chemical shifts of xenon in the voids of zeolite Y with O%, 53%, 75%, and 95% exchange of copper (II) for sodium ions were determined. With increasing copper content the shifts go uptield. The local chemical shifts of xenon at a crystallographic SII site with a

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experiments we have determined values of the mean free path 1 of xenon adsorbed on various zeolites. We deduce from them the dependence of the chemical shift S on 1. It is now possible to determine the dimensions of any cavity in which xenon can be adsorbed.