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The relation betwen the 129Xe NMR chemical shifts of xenon in the zeolites NaX, NaY and CuNaY

✍ Scribed by B. Boddenberg; M. Hartmann

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 344 KB
Volume: 203
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)85395-5

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✦ Synopsis

The adsorption isotherms and lz9Xe NMR chemical shifts of xenon in the voids of zeolite Y with O%, 53%, 75%, and 95% exchange of copper (II) for sodium ions were determined. With increasing copper content the shifts go uptield. The local chemical shifts of xenon at a crystallographic SII site with and without the charge compensating sodium ion are concluded to be 60 and 32 ppm, respectively. ' To whom correspondence should be addressed.

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