NMF effect on photosensitized charge separation using partially quaternized poly(1-vinylimidazole)-bound ruthenium(II) complexes
β Scribed by Masahiro Suzuki; Naoki Yokoyama; Mutsumi Kimura; Kenji Hanabusa; Hirofusa Shirai
- Book ID
- 104425676
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 186 KB
- Volume
- 40
- Category
- Article
- ISSN
- 1381-5148
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β¦ Synopsis
The solvent effects on the photosensitized charge separation using partially quaternized poly(1-vinylimidazole)-bound ruthenium(II) complexes (RuQPIm), in which bis(2,29-bipyridine)ruthenium(II) complexes are coordinated to the imidazolyl residues on the poly(1-vinylimidazole) partially quaternized by 1-bromohexadecane and the degree of quaternization is 19 (RuQPIm-19) and 44 (RuQPIm-44) molar percentage, have been investigated in methanol and methanol-NMF (NMF:
π SIMILAR VOLUMES
## Abstract Metallopolymers in which bis(2,2β²βbipyridine)ruthenium(II) complexes are coordinated to imidazolyl residues on partially quaternized poly(1βvinylimidazole) having different degree of quaternization (RuQPIm) were synthesized. The luminescence quenching of the photoexcited RuQPIms with va
A series of ruthenium(II) complex-containing partially quaternized poly(1vinylimidazole)s with various alkyl side chains such as hexyl (C 6 RuQPIm), dodecyl (C 12 RuQPIm), and hexadecyl (C 16 RuQPIm) were synthesized. The effects of L-tyrosine esters with hexyl (C 6 Tyr), octyl (C 8 Tyr), and dodecy