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NMF effect on photosensitized charge separation using partially quaternized poly(1-vinylimidazole)-bound ruthenium(II) complexes

✍ Scribed by Masahiro Suzuki; Naoki Yokoyama; Mutsumi Kimura; Kenji Hanabusa; Hirofusa Shirai


Book ID
104425676
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
186 KB
Volume
40
Category
Article
ISSN
1381-5148

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✦ Synopsis


The solvent effects on the photosensitized charge separation using partially quaternized poly(1-vinylimidazole)-bound ruthenium(II) complexes (RuQPIm), in which bis(2,29-bipyridine)ruthenium(II) complexes are coordinated to the imidazolyl residues on the poly(1-vinylimidazole) partially quaternized by 1-bromohexadecane and the degree of quaternization is 19 (RuQPIm-19) and 44 (RuQPIm-44) molar percentage, have been investigated in methanol and methanol-NMF (NMF:


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Luminescence quenching of partially quat
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## Abstract Metallopolymers in which bis(2,2′‐bipyridine)ruthenium(II) complexes are coordinated to imidazolyl residues on partially quaternized poly(1‐vinylimidazole) having different degree of quaternization (RuQPIm) were synthesized. The luminescence quenching of the photoexcited RuQPIms with va

Effects of L-tyrosine esters on quenchin
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A series of ruthenium(II) complex-containing partially quaternized poly(1vinylimidazole)s with various alkyl side chains such as hexyl (C 6 RuQPIm), dodecyl (C 12 RuQPIm), and hexadecyl (C 16 RuQPIm) were synthesized. The effects of L-tyrosine esters with hexyl (C 6 Tyr), octyl (C 8 Tyr), and dodecy