The solvent effects on the photosensitized charge separation using partially quaternized poly(1-vinylimidazole)-bound ruthenium(II) complexes (RuQPIm), in which bis(2,29-bipyridine)ruthenium(II) complexes are coordinated to the imidazolyl residues on the poly(1-vinylimidazole) partially quaternized
Acetonitrile effects on quenching and photosensitized charge separation using partially quaternized poly(1-vinylimidazole)-bound ruthenium(II) complexes
β Scribed by Masahiro Suzuki; Naoki Yokoyama; Mutsumi Kimura; Kenji Hanabusa; Hirofusa Shirai
- Book ID
- 102663086
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 691 KB
- Volume
- 199
- Category
- Article
- ISSN
- 1022-1352
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## Abstract Metallopolymers in which bis(2,2β²βbipyridine)ruthenium(II) complexes are coordinated to imidazolyl residues on partially quaternized poly(1βvinylimidazole) having different degree of quaternization (RuQPIm) were synthesized. The luminescence quenching of the photoexcited RuQPIms with va
A series of ruthenium(II) complex-containing partially quaternized poly(1vinylimidazole)s with various alkyl side chains such as hexyl (C 6 RuQPIm), dodecyl (C 12 RuQPIm), and hexadecyl (C 16 RuQPIm) were synthesized. The effects of L-tyrosine esters with hexyl (C 6 Tyr), octyl (C 8 Tyr), and dodecy