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Nitrososynthase-Triggered Oxidative Carbon–Carbon Bond Cleavage in Baumycin Biosynthesis

✍ Scribed by Al-Mestarihi, Ahmad; Romo, Anthony; Liu, Hung-wen; Bachmann, Brian O.

No coin nor oath required. For personal study only.

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## Abstract Substrates with aliphatic substituents at the cyclopropenyl core undergo oxidation with formation of 2 ketols [cf.