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Aromatic Cations from Oxidative Carbon–Hydrogen Bond Cleavage in Bimolecular Carbon–Carbon Bond Forming Reactions

✍ Scribed by Clausen, Dane J.; Floreancig, Paul E.


Book ID
111933129
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
772 KB
Volume
77
Category
Article
ISSN
0022-3263

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Homogeneous isomerisation of 1 -pen tene to 2-cisand 2-trans-pentene occurs in presence of dodecacarbonyltriosmium. A contemporaneous formation of compounds of molecular formula H0s3(C0),&H, and HzOs3(CO)&,HS can be observed. The structures of these complexes are discussed. An analogous behaviour is