Cleavage of carbon-hydrogen bonds in reactions of dodecacarbonyltriosmium with pentenes and hexenes

✍ Scribed by R.P. Ferrari; G.A. Vaglio

• Book ID: 104139205
• Publisher: Elsevier Science
• Year: 1976
• Tongue: English
• Weight: 315 KB
• Volume: 20
• Category: Article
• ISSN: 0020-1693
• DOI: 10.1016/s0020-1693(00)94106-9

✦ Synopsis

Homogeneous isomerisation of 1 -pen tene to 2-cisand 2-trans-pentene occurs in presence of dodecacarbonyltriosmium. A contemporaneous formation of compounds of molecular formula H0s3(C0),&H, and HzOs3(CO)&,HS can be observed. The structures of these complexes are discussed. An analogous behaviour is shown. by dodecacarbonyltriosmium in its reactions with hexenes.