Nitrosobenzene cross-dimerization: Structural selectivity in solution and in solid state

✍ Scribed by Ivana Biljan; Gorana Cvjetojevic; Vilko Smrecki; Predrag Novak; Gregor Mali; Janez Plavec; Darko Babic; Zlatko Mihalic; Hrvoj Vancik

• Publisher: Elsevier Science
• Year: 2010
• Tongue: English
• Weight: 441 KB
• Volume: 979
• Category: Article
• ISSN: 0022-2860
• DOI: 10.1016/j.molstruc.2010.05.034

✦ Synopsis

Possibility of nitrosobenzenes to form dimeric molecular structures (azodioxides) is used as a model for intermolecular selectivity investigations in solution as well as in solid state. Cross-dimerization of different combinations of p-and m-substituted nitrosobenzene pairs was studied by variable temperature 1 H NMR, solid-state NMR (CP MAS), IR, and ab initio calculations. It is evident that p-nitronitrosobenzene behaves nonselectively because it forms dimers with all the studied nitrosobenzene partners. In contrast, p-methoxynitrosobenzene in most cases does not form dimers. The evidence that ability to form dimers is different in solution than in the solid state can be explained by influence of molecular arrangements in the crystal lattice.