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Nitrosation of ascorbic acid by nitrite ion in unbuffered neutral and moderately acidic aqueous solutions

✍ Scribed by V. S. Konyaeva; A. E. Myshkin; K. Z. Gumargalieva; Yu. V. Moiseev


Book ID
112424142
Publisher
Springer
Year
1992
Tongue
English
Weight
387 KB
Volume
41
Category
Article
ISSN
1573-9171

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Mechanism of the oxidation ofL-ascorbic
✍ Donovan A. Dixon; Novelette P. Sadler; Tara P. Dasgupta πŸ“‚ Article πŸ“… 1995 πŸ› Springer 🌐 English βš– 421 KB

The kinetics of oxidation of L-ascorbic acid (H2A) by the mononuclear complex [Co(NH3)5(OH2)] (C103) 3 have been studied spectrophotometrically at 490nm. The mechanism involves single one-electron transfers involving the pentaamminehydroxo complex and the ascorbate anions (HA-and A 2 ), subsequent f