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Mechanism of the oxidation of l-ascorbic acid by the molyb-datopentaamminecobalt(III) ion in aqueous solution

โœ Scribed by Alvin A. Holder; Tara P. Dasgupta; Sang-Choul Im

Book ID
110371504
Publisher
Springer
Year
1997
Tongue
English
Weight
181 KB
Volume
22
Category
Article
ISSN
0340-4285

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Mechanism of the oxidation ofL-ascorbic
Mechanism of the oxidation ofL-ascorbic acid by the pentaammineaquacobalt(III) ion in aqueous solution
โœ Donovan A. Dixon; Novelette P. Sadler; Tara P. Dasgupta ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Springer ๐ŸŒ English โš– 421 KB

The kinetics of oxidation of L-ascorbic acid (H2A) by the mononuclear complex [Co(NH3)5(OH2)] (C103) 3 have been studied spectrophotometrically at 490nm. The mechanism involves single one-electron transfers involving the pentaamminehydroxo complex and the ascorbate anions (HA-and A 2 ), subsequent f