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Mechanism of the oxidation of L-ascorbic acid by the bis(pyridine-2,6-dicarboxylate)cobaltate(III) ion in aqueous solution

โœ Scribed by Alvin A. Holder; Ross F. G. Brown; Sophia C. Marshall; Vince C. R. Payne; Maria D. Cozier; Walter A. Alleyne; Christopher O. Bovell


Book ID
110246742
Publisher
Springer
Year
2000
Tongue
English
Weight
129 KB
Volume
25
Category
Article
ISSN
0340-4285

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Mechanism of the oxidation ofL-ascorbic
โœ Donovan A. Dixon; Novelette P. Sadler; Tara P. Dasgupta ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Springer ๐ŸŒ English โš– 421 KB

The kinetics of oxidation of L-ascorbic acid (H2A) by the mononuclear complex [Co(NH3)5(OH2)] (C103) 3 have been studied spectrophotometrically at 490nm. The mechanism involves single one-electron transfers involving the pentaamminehydroxo complex and the ascorbate anions (HA-and A 2 ), subsequent f