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Nitrosation cleavage of hexamethylenetetramine in slightly acid medium from the aspect of the thermochemistry of the nitrosation agent formation

✍ Scribed by Svatopluk Zeman; Milan Dimun

Book ID: 103416528
Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 705 KB
Volume: 51
Category: Article
ISSN: 0040-6031
DOI: 10.1016/0040-6031(81)85170-2

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0-Deprotonation of 3 is, ofcourse, possible too. It is even more dominant than N-deprotonation for obvious reasons. It can be neglected, however, in this context, because 0 -deprotonation is a side-equilibrium which does not lead to the reaction product NzO.