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Kinetic study of the nitrosation of 1,1,3-trimethylurea in aqueous acid medium

✍ Scribed by F. J. Lona-Ramírez; R. Herrera-Muñoz; V. Rico-Ramírez; F. Louvier Hernández; G. Luna-Bárcenas; G. González-Alatorre

Book ID: 113078712
Publisher: Springer-Verlag
Year: 2011
Tongue: English
Weight: 317 KB
Volume: 105
Category: Article
ISSN: 1878-5190
DOI: 10.1007/s11144-011-0390-4

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The rate constants were determined for the nitrosation reactions of the following substrates: Methyl (MU), Ethyl (EU),Propyl (PU)Butyl (BU), and Allylurea (AU). The rate equation found at a constant pH was: [Urea]. The reactions were carried out in pre-v ϭ k[HNO ] 2 dominantly organic media(dioxane