The rate constants were determined for the nitrosation reactions of the following substrates: Methyl (MU), Ethyl (EU),Propyl (PU)Butyl (BU), and Allylurea (AU). The rate equation found at a constant pH was: [Urea]. The reactions were carried out in pre-v ϭ k[HNO ] 2 dominantly organic media(dioxane
✦ LIBER ✦
Kinetic study of the nitrosation reaction of 1,3-dimethylurea in dioxane?water mixtures
✍ Scribed by Bravo, Carlos; Herv�s, Pablo; Iglesias, Emilia; Leis, J. Ram�n; Pe�a, M. Elena
- Book ID
- 121224231
- Publisher
- Royal Society of Chemistry
- Year
- 1990
- Tongue
- English
- Weight
- 640 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1472-779X
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## Abstract The kinetics of the nitrosation of 1,3‐dimethyl (DMU), 1,3‐diethyl (DEU), 1,3‐dipropylurea (DPU), 1,3‐dibuthyl (DBU), and 1,3‐diallylurea (DAU) were studied in a conventional UV/vis spectrophotometer in aqueous‐perchloric acid media. The kinetic study was carried out using the initial r