Nitrogen oxides/selenium dioxide-mediated benzylic oxidations
โ Scribed by Joseph E. Remias; Ayusman Sen
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 103 KB
- Volume
- 201
- Category
- Article
- ISSN
- 1381-1169
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๐ SIMILAR VOLUMES
Selenium dioxide occupies a unique position a5 au olefln oxidant since the oxidstion product is an e.Uylic alcohol or a derivative of that alcohol such as en ether or an ester; ketone fomation is also occasionally observed. We now report the results of a sidy on the oxidation of 1,3\_dlphenylpmpene
Experimental evidence was obtained which showed that the chromium content of type 316 stainless steel can catalyse the oxidation of NO to NO2 due to a chromium oxide transition between 400 ยฐC and 600 ยฐC. Carbon monoxide was shown to inhibit this oxidation but only in concentrations above 0.1%. Expla