Nitrogen Fixation by Transition Metal Complexes
β Scribed by VOL'PIN, M. E.; SHUR, V. B.
- Book ID
- 109647399
- Publisher
- Nature Publishing Group
- Year
- 1966
- Tongue
- English
- Weight
- 133 KB
- Volume
- 209
- Category
- Article
- ISSN
- 0028-0836
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π SIMILAR VOLUMES
Nitrogen heterocycles, such as pyrroles, phthalimidines and pyridines, are synthesized starting from the ligating dinitrogen in Mo and W complexes of the type [M(N 2 ) 2 (L) 4 ] (M =Mo, W; L= phosphine). Further, ammonia is formed from N 2 and H 2 at 55Β°C and 1 atm by using a novel Ru/W bimetallic s
## Abstract Studies regarding the transition-metal-catalyzed decomposition of nitrogen derivatives toward Curtius rearrangement and the formation of nitrenes which undergo C-H insertion and aziridination reactions are presented. These processes lead to the formation of C-N bond with a high level of