Catalytic activation of nitrogen derivatives with transition-metal complexes

✍ Scribed by Lebel, Hélène; Leogane, Olivier; Huard, Kim; Lectard, Sylvain

• Book ID: 111902041
• Publisher: International Union of Pure and Applied Chemistry
• Year: 2006
• Tongue: English
• Weight: 275 KB
• Volume: 78
• Category: Article
• ISSN: 0033-4545
• DOI: 10.1351/pac200678020363

✦ Synopsis

Abstract

Studies regarding the transition-metal-catalyzed decomposition of nitrogen derivatives toward Curtius rearrangement and the formation of nitrenes which undergo C-H insertion and aziridination reactions are presented. These processes lead to the formation of C-N bond with a high level of selectivity and efficiency.