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Nitrogen-15 nuclear magnetic resonance spectra of isocyanates, isothiocyanates and N-sulfinylamines

✍ Scribed by Issa Yavari; John S. Staral; John D. Roberts

Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
257 KB
Volume
12
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The ^15^N NMR spectra of ten isocyanates, four isothiocyanates, and four N‐sulfinylamines have been obtained at the natural‐abundance level by high‐resolution NMR spectroscopy. The results show that isocyanates and isothiocyanates have ^15^N chemical shifts over 200 ppm toward higher fields compared to those of N‐sulfinylamines. The sensitivity of the ^15^N shifts in these substances to substituent and electronic effects are discussed.

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