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Nitrile sulfides. Synthesis of 1,2,4-thiadiazoles

โœ Scribed by Howe, Robert K.; Franz, John E.


Book ID
120826582
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
427 KB
Volume
39
Category
Article
ISSN
0022-3263

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Photocycloaddition of arylcarbothioamide
โœ Minoru Machida; Kazuaki Oda; Yuichi Kanaoka ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 140 KB

On irradiation arylcarbothioamides (l\_) undergo, in the absence of oxygen, the Paterno-BUchi reaction with olefins followed by cleavage, whereas under aerobic conditions the photoreaction proceeds to give 4 and 5 probably via nitrile sulfide intermediates. Although the photochemistry of thione has