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Synthesis of 3-thienyl-substituted isothiazolines-2 and 1,2,4-thiadiazoles based on nitrile sulfides of the thiophene series

โœ Scribed by M. M. Krayushkin; M. A. Kalik; A. Ya. Kudryavtseva


Book ID
112424220
Publisher
Springer
Year
1992
Tongue
English
Weight
459 KB
Volume
41
Category
Article
ISSN
1573-9171

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Photocycloaddition of arylcarbothioamide
โœ Minoru Machida; Kazuaki Oda; Yuichi Kanaoka ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 140 KB

On irradiation arylcarbothioamides (l\_) undergo, in the absence of oxygen, the Paterno-BUchi reaction with olefins followed by cleavage, whereas under aerobic conditions the photoreaction proceeds to give 4 and 5 probably via nitrile sulfide intermediates. Although the photochemistry of thione has