Anodic oxidation of naphthalene in an electrolyte of methanol and potassium hydroxide via I-methoxynaphthalene yields 1,4-and 1,2-dimethoxynaphthalene as well as 1,2,4\_trimethoxynaphthalene. The latter two compounds are also obtained starting from Z-methoxynaphthalene. ALLGEMEINRR TEIL Zm Gegensatz
✦ LIBER ✦
Nitrierung von 1- und 2-Methoxymethyl-naphthalin
✍ Scribed by Diether G. Markees
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- German
- Weight
- 217 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
2‐Methoxymethyl naphthalene (1) was synthesized and its properties were found to be different from those reported in the literature. The reaction of this compound with cold conc. nitric acid gave 8‐nitro‐2‐naphthaldehyde (2). When 1‐methoxymethyl naphthalene (4) was treated similarly 4‐nitro‐1‐methoxymethyl naphthalene (5) and 8‐nitro‐1‐naphthaldehyde (6) were obtained.
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