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Nitridosilicates-A Significant Extension of Silicate Chemistry

✍ Scribed by Wolfgang Schnick; Hubert Huppertz

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
772 KB
Volume
3
Category
Article
ISSN
0947-6539

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✦ Synopsis

Because of its low chemical reactivity Si,N, has hardly been used as a starting material for the preparation of multinary silicon nitridcs or nitridosilicates, but has gained increasing importance as a nonoxidic material for high-performance applications. A novel synthetic approach is presented, which starts from silicon diimide (Si(NH),) and makes available a large variety of novel nitridosilicates. The structures of these nitridosilicates represent a significant extension from those found in the family of oxosilicates. Because of their outstanding chemical and physical stability, nitridosilicates might be of particular interest for the development of novel inorganic nitridic materials.

Keywords

high-temperature synthesis * materials science . nitridosilicates * nitrogen silicon [

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