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Nitrations with Acetyl Nitrate. III. Nitration with 1,1-Diarylalkenes 1

✍ Scribed by Bordwell, Frederick G.; Garbisch, Edgar W.


Book ID
125486825
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
913 KB
Volume
27
Category
Article
ISSN
0022-3263

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N-acetyl enamines undergo nitration at the double bond. Products of further nitration and oxidation in an allylic position are also formed. Sterically unhindered enamide, N-acetyl-eholest-2-en-3-amine, yields oxadiazole, as one of the reaction products.