Nitration of N-acetyl enamines with acetyl nitrate

✍ Scribed by Jacek W. Morzycki; Zenon Łotowski; Monika Stȩpniowska; Agnieszka Gryszkiewicz; Agnieszka Z. Wilczewska

• Book ID: 104208186
• Publisher: Elsevier Science
• Year: 1997
• Tongue: French
• Weight: 432 KB
• Volume: 53
• Category: Article
• ISSN: 0040-4020
• DOI: 10.1016/s0040-4020(97)10074-6

✦ Synopsis

N-acetyl enamines undergo nitration at the double bond. Products of further nitration and oxidation in an allylic position are also formed. Sterically unhindered enamide, N-acetyl-eholest-2-en-3-amine, yields oxadiazole, as one of the reaction products.