The chemistry of nine-atom deltahedral Zintl anions of Group 14 has advanced greatly in recent years. Redox reactions of these clusters have led to dimers, trimers, tetramers, and infinite chains of germanium clusters such as [Ge 9 -Ge 9 ] 6À , [1] [Ge 9 =Ge 9 =Ge 9 ] 6À , [2] [Ge 9 =Ge 9 =Ge 9 =Ge
✦ LIBER ✦
[(Ni—Ni—Ni)@(Ge9)2]4-: A Linear Triatomic Nickel Filament Enclosed in a Dimer of Nine-Atom Germanium Clusters.
✍ Scribed by Jose M. Goicoechea; Slavi C. Sevov
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 14 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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[(Ni-Ni-Ni)@(Ge9)2]4−: A Linear Triatomi
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The chemistry of nine-atom deltahedral Zintl anions of Group 14 has advanced greatly in recent years. Redox reactions of these clusters have led to dimers, trimers, tetramers, and infinite chains of germanium clusters such as [Ge 9 -Ge 9 ] 6À , [1] [Ge 9 =Ge 9 =Ge 9 ] 6À , [2] [Ge 9 =Ge 9 =Ge 9 =Ge