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[(Ni-Ni-Ni)@(Ge9)2]4−: A Linear Triatomic Nickel Filament Enclosed in a Dimer of Nine-Atom Germanium Clusters

✍ Scribed by Jose M. Goicoechea; Slavi C. Sevov


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
370 KB
Volume
117
Category
Article
ISSN
0044-8249

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✦ Synopsis


The chemistry of nine-atom deltahedral Zintl anions of Group 14 has advanced greatly in recent years. Redox reactions of these clusters have led to dimers, trimers, tetramers, and infinite chains of germanium clusters such as [Ge 9 -Ge 9 ] 6À , [1] [Ge 9 =Ge 9 =Ge 9 ] 6À , [2] [Ge 9 =Ge 9 =Ge 9 =Ge 9 ] 8À , [3,4]


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[(Ni-Ni-Ni)@(Ge9)2]4−: A Linear Triatomi
✍ Jose M. Goicoechea; Slavi C. Sevov 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 370 KB 👁 1 views

The chemistry of nine-atom deltahedral Zintl anions of Group 14 has advanced greatly in recent years. Redox reactions of these clusters have led to dimers, trimers, tetramers, and infinite chains of germanium clusters such as [Ge 9 -Ge 9 ] 6À , [1] [Ge 9 =Ge 9 =Ge 9 ] 6À , [2] [Ge 9 =Ge 9 =Ge 9 =Ge