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Nickel-induced conversion of carbon-oxygen into carbon-carbon bonds. One-step transformations of enol ethers into olefins and aryl ethers into biaryls

✍ Scribed by Wenkert, Ernest; Michelotti, Enrique L.; Swindell, Charles S.


Book ID
120024794
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
262 KB
Volume
101
Category
Article
ISSN
0002-7863

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Allyl ethyl carbonate/palladium (0), a n
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Alcohols are converted in a one-step procedure into ally1 ethers under neutral conditions, using ally1 ethyl carbonate in the presence of a catalytic amount of palladium (0). Anomeric hydroxyls are selectively allylated in the presence of other hydroxyl groups. Ally1 groups have been found to be of