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Nickel catalyzed reactions involving strained bonds. X. Nickel(0) catalyzed cycloaddition of bicyclo[2.1.0]pentane and olefins. Contrasting stereochemistry of the thermal and transition metal catalyzed reactions

✍ Scribed by Noyori, R.; Kumagai, Y.; Takaya, H.


Book ID
126984326
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
309 KB
Volume
96
Category
Article
ISSN
0002-7863

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Stereochemistry of the nickel(0) catalyz
✍ R. Noyori; H. Kawauchi; H. Takaya πŸ“‚ Article πŸ“… 1974 πŸ› Elsevier Science 🌐 French βš– 191 KB

Bicyclo[l.l.O]butanes upon interaction with nickel(O) catalysts undergo the intramolecular retro-carbene addition to produce reactive allylcarbene-nickel(O) intermediates, which in turn cycloadd intermolecularly, in a formal sense, across an electron-poor carbon-carbon double bond giving the cyclopr