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Nickel Catalysis in the Stereoselective Preparation of Quinolizidine, Pyrrolizidine, and Indolizidine Alkaloids: Total Synthesis of (+)-Allopumiliotoxin 267A

✍ Scribed by Tang, Xiao-Qing; Montgomery, John

Book ID
121264442
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
56 KB
Volume
121
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Nickel-Catalyzed Pr
ChemInform Abstract: Nickel-Catalyzed Preparation of Bicyclic Heterocycles: Total Synthesis of (+)-Allopumiliotoxin 267A, (+)-Allopumiliotoxin 339A, and (+)-Allopumiliotoxin 339B.
✍ Xiao-Qing Tang; John Montgomery πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 36 KB πŸ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

Highly Stereoselective trans Addition of
Highly Stereoselective trans Addition of Ο€-Type Nucleophiles to a Bicyclic N-Acyliminium Ion – Application to the Synthesis of Indolizidine and Pyrrolizidine Alkaloids
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Enantiopure bicyclic 5-ethoxytetrahydropyrrolo[1,2-c]oxa-disubstituted pyrrolidines was illustrated by formal syntheses of 3,5-disubstituted indolizidine toxins, starting from 5-zol-3-one 1b was prepared in two steps from the known tosylate 4, which is readily available from (S)-pyroglutamic allylte