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Nickel-catalysed aromatic Finkelstein reaction of aryl and heteroaryl bromides

✍ Scribed by Cant, Alastair A.; Bhalla, Rajiv; Pimlott, Sally L.; Sutherland, Andrew

Book ID
120158538
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
675 KB
Volume
48
Category
Article
ISSN
1359-7345

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Nickel-catalysed synthesis of 3-chloroan
Nickel-catalysed synthesis of 3-chloroanilines and chloro aminopyridines via cross-coupling reactions of aryl and heteroaryl dichlorides with amines
✍ Christophe Desmarets; RaphaΓ«l Schneider; Yves Fort πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 87 KB

Selective monoamination of aryl and heteroaryl dichlorides has been carried out using a catalyst combination of Ni(0) associated to 2,2%-bipyridine. The synthesis of novel 3-chloroanilines and chloro aminopyridines in good to excellent yields is allowed using an excess of amine, 10 or 20 mol% cataly