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Ni-Catalyzed Carboxylation of Unactivated Primary Alkyl Bromides and Sulfonates with CO 2

✍ Scribed by Liu, Yu; Cornella, Josep; Martin, Ruben


Book ID
125808427
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
855 KB
Volume
136
Category
Article
ISSN
0002-7863

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Ni-Catalyzed Reductive Allylation of Una
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Game of two electrophiles: Two partially positively charged sp(3) carbon atoms can be connected by using a catalytic Ni species in the presence of an environmentally benign Zn reductant, delivering allylated alkanes. This unprecedented approach allowed a variety of unactivated alkyl halides and subs