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[(NHC)AuI]-Catalyzed Rearrangement of Allylic Acetates.

โœ Scribed by Nicolas Marion; Ronan Gealageas; Steven P. Nolan


Book ID
102005017
Publisher
John Wiley and Sons
Year
2007
Weight
32 KB
Volume
38
Category
Article
ISSN
0931-7597

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Palladium (II) - catalyzed rearrangement
โœ Larry E. Overman; Fredrick M. Knoll ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 191 KB

We recently reported that mercuric trifluoroacetate was an effective catalyst for equilibrating carbamic esters of allylic alcohols at room temperature (1 8 3, X= NMe2). 394 Yields were uniformly high, and side-reactions (elimination, cyclization, &d sk2eta.l rearrangement) occasionally encountered