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[(NHC)Au I ]-Catalyzed Rearrangement of Allylic Acetates

โœ Scribed by Marion, Nicolas; Gealageas, Ronan; Nolan, Steven P.


Book ID
126098145
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
104 KB
Volume
9
Category
Article
ISSN
1523-7060

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โœ Larry E. Overman; Fredrick M. Knoll ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 191 KB

We recently reported that mercuric trifluoroacetate was an effective catalyst for equilibrating carbamic esters of allylic alcohols at room temperature (1 8 3, X= NMe2). 394 Yields were uniformly high, and side-reactions (elimination, cyclization, &d sk2eta.l rearrangement) occasionally encountered