New type of radical in irradiated single crystals of carboxylic acids
โ Scribed by Iwasaki, Machio.; Eda, Bunzo.; Toriyama, Kazumi.
- Book ID
- 126192431
- Publisher
- American Chemical Society
- Year
- 1970
- Tongue
- English
- Weight
- 263 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
A single crystal ESR study of the title compound shows that the oxy radical R-O-is sIecCivety formed in one of the two OH groups attached to the same carbon atom. in relation to this observation, selective formation of radicals in some symmetrical molecules is discussed. ft is susested that a sIight
An alkoxy radical has been mvestlgated by ESR III smgle crystals of rhamnose u-radiated and measured at 77 K. Two pmton hyperfme couplings, ap = 40 G and ar = 14 G. are observed The prmclpai values of theg tensor are 2.CM56.2 0064 and 2 0032. The mechamsm of formatlon is briefly dlscussed.