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New Titanium(IV) Complexes with 2-Cyclopentadienylbenzylamido Ligands: Synthesis, Characterization, and Catalytic Properties for Ethylene Polymerization and Copolymerization with 1-Hexene

✍ Scribed by Tao, Xin; Wu, Qiaolin; Huo, Hang; Gao, Wei; Mu, Ying

Book ID: 120546257
Publisher: American Chemical Society
Year: 2013
Tongue: English
Weight: 327 KB
Volume: 32
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om4003945

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## Abstract A number of new half‐sandwich titanium(IV) complexes of the type [Cp′TiCl~2~{N(2,6‐R^1^~2~C~6~H~3~)R^2^}] [R^1^ = __i__Pr (1, 2, 4), Me (3, 5); R^2^ = Me (1, 3, 4, 5), Bn (2); Cp′ = Cp (1, 2, 3), Cp\* (4, 5)] have been synthesized by the reaction of [Cp′TiCl~3~] with the lithium salts o