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Binuclear zirconium complexes with bidentate N-(ortho-dimethylaminobenzyl)anilide ligands: Synthesis, characterization, and catalytic properties for ethylene polymerization and copolymerization with 1-hexene

✍ Scribed by Liu, Kefeng; Wu, Qiaolin; Mu, Xindong; Gao, Wei; Mu, Ying

Book ID
122003849
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
323 KB
Volume
52
Category
Article
ISSN
0277-5387

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Half-Titanocence Anilide Complexes Cp′TiCl2[N(2,6-R12C6H3)R2]: Synthesis, Structures and Catalytic Properties for Ethylene Polymerization and Copolymerization with 1-Hexene
✍ Kefeng Liu; Qiaolin Wu; Wei Gao; Ying Mu; Ling Ye 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 516 KB

## Abstract A number of new half‐sandwich titanium(IV) complexes of the type [Cp′TiCl~2~{N(2,6‐R^1^~2~C~6~H~3~)R^2^}] [R^1^ = __i__Pr (1, 2, 4), Me (3, 5); R^2^ = Me (1, 3, 4, 5), Bn (2); Cp′ = Cp (1, 2, 3), Cp\* (4, 5)] have been synthesized by the reaction of [Cp′TiCl~3~] with the lithium salts o