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New synthetic methods. 1,3-Alkylative carbonyl transposition

โœ Scribed by Trost, Barry M.; Stanton, James L.


Book ID
125960771
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
996 KB
Volume
97
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


A Simple Alkylative 1,2-Carbonyl Transpo
โœ Wolfgang Oppolzer; Tarun Sarkar; Kumar K. Mahalanabis ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 577 KB

## Abstract Acid catalysed dehydration of the diols **5**, derived from the cyclohexenone **3** affords mixtures of **8** and **11**. The product ratio **8/11**, although strongly dependent on both the reaction conditions and the substituent R, is independent of the diol configuration; this indicat