Electroorganic chemistry. 68. A new method of 1,4-transposition of a carbonyl group
β Scribed by Shono, Tatsuya; Kashimura, Shigenori
- Book ID
- 127205717
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 174 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
A new and efficient 1,2-carbonyl transposition procedure for the formation of 2-keto pleuromutilin compounds is described. The synthetic sequence is performed in four steps and 26% overall yield.
A variety of 1,3-oxathiolanes undergo a benzyne-induced fragmentation leading to phenyl vinyl sulfides and carbonyl compounds. The reaction developed here provides a novel method for deprotection of carbonyl compounds from 1,3-oxathiolanes, preparation of phenyl vinyl sulfides, and 1,2-carbonyl tran
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