New Synthetic Approaches to Symmetrical Sulfur-Bridged Carbocycles
β Scribed by Corey, E. J.; Block, Eric
- Book ID
- 127243792
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 918 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
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Symmetrical and photochromic diarylperfluorocyclopentene has been prepared by reaction of 3-1ithio-5-chloro-2-methylthiophene with the ethyl ester of hexafluoroglutaric acid, followed by ring closure via a McMurry coupling. Compound 7 is a versatile intermediate for the development of photochromic m